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Unravelling Formaldehyde Metabolism in Bacteria: Road towards Synthetic Methylotrophy

Synthetic polymers—including PSPMA/PSSS polymer brushes, sulfonated glycopolymers, zwitterionic hydrogel networks, sulfonated natural polysaccharides, and the new generation of sulfonated polypeptides, polyesters, and polyglycerols—enable independent tuning of charge density, degree and topology of sulfation, chain length, and degradability

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For example, accurate mass measurements of the ions of m/z 457 and m/z 460 were within 5 ppm of expected formula C 18 H 24 N 4 O 8 S, and both conjugates shared a common fragment ion of m/z 382 (Figure 4), which represented the loss of labeled/unlabeled glycine from the GSH moiety